Sol-Gel

 March 2001
Sol-Gel Process
A special Issue of the Journal of the French Glass Institute "Verre"
Verre, Vol 6, N°5 p12-43, 2000

Jacques Livage the guest editor of this issue make the status of the current research in sol-gel directed especially  to the glass industry. Below the complete list of the papers in this issue
The sol-gel process (in French) 
by J. Livage
The sol-gel process developed at CEA: "soft chemistry" used for Laser glass coatings (in French)
by Philippe Belleville
Sol-Gel film to functionalize glass (in French)
by J.P. Boilot, F. Chaput, T. Gacoin
Protavic SG FP, sol-gels for thin film coating with fast photochromic response (in French)
by B. Sahut, P. Roy
Functional coatings obtained on glass by sol-gel processes (in French)
By M.A. Aegerter, M. Mennig, P. Müller, H. Schmidt
Decoration of crystal glassware via hybrid sol-gel coatings
by G. Schottner, J. Kron, K.J. Deichmann
The sol-gel process in art conservation the long term protection of the Last Judgement mosaic in Prague
by E. Bescher, J.D. Mackenzie

 


Behavior of organic compounds confined in monoliths of sol-gel silica glass. Effects of guest-host hydrogen bonding on uptake, release, and isomerization of the guest compounds
J.D. Badjic and N.M. Kostic
J. Mater. Chem, 11, 408-418, 2001

Specific interaction between the host matrix and the guest molecules may restrict or broaden the applicability of doped sol-gel glasses in chemistry, biochemistry and materials science. This work emphasize on the effect of hydrogen bonding and its impact on uptake and release of solutes from solutions. Those who work on sensors based on entrapped active molecules on sol-gel matrix will found this lecture extremely useful

Related links &  readings :

Sensor preparation by sol-gel technology 
Center for Interface Analysis and Sensors University of Tuebingen (Germany)
Fiber-Optic Sol-Gel Sensors
by Dr. Jie Lin from Portland State University

Polymer-Layered Silicate Nanocomposite Light-Emitting Devices
T..W. Lee, J. Yoon and J.J. Kim
Adv. Mater. 13, N°3, 211-213, 2001

The potential use of polymer LEDs is ultimately limited by low quantum efficiency and poor stability against oxygen and humidity. The authors present a nanostructured composite material consisting of conjugated polymers  (MEH-PPV) and layered inorganic silicates which shows an enhancement of the quantum efficiency of 100x in comparison to the polymer itself and improved PL intensity by a factor 18.

Related links &  readings :


Organic LEDs

Fabrication and Study of Polymer Light Emitting Devices
Physics Dept. Ohio-State University
Synthesis of conjugated polymers for light-emitting diodes (LED:s), photovoltaic diodes and polymer lasers
University of Chalmers (Sweden)

Inorganic LEDs

Inorganic 
References & Links on LEDs
from the Materials Research Science and Engineering Center of University of Wisconsin
Blue Chip :Shuji Nakamura beat the titans to blue LEDs and Lasers potentially revolutionizing lighting and data storage (Feature article)
The profile of the Blue LEDs inventor 
by Glenn Zorpette 
Source:  Scientific American

Layered silicates

Southern Clay Products
Nanoclay

Hybrid Organic-Inorganic Materials- In Search of Synergic Activity
P.Gomez-Romero
Adv. Mater. 13, N°3, 163-174, 2001

This review paper surveys the work developed in the field of functional hybrid materials especially those containg conducting organic polymers, in combination with a variety of inorganic species, from molecular to extended phases, including clusters and nanosized inorganic particles [304 References]

Related links & readings:  

Pedro Gomez-Romero home page
Hybrids what they are ?
New Nanocomposites : Putting organic function "inside" the channel walls of periodic mesoporous silica
Hybrid Inorganic-Organic Mesoporous Silicates-Nanoscopic Reactors Coming of Age

Nanoengineering of particle surfaces
F. Caruso

Adv. Mater. 13, N°3, 163-174, 2001

The creation of core-shell particles is attracting a great deal of interest because of the diverse applicability of these colloidal particles; e.g., as building blocks for photonic crystals, in multi-enzyme biocatalysis, and in drug delivery. This review presents the state-of-the-art in strategies for engineering particle surfaces. [140 references]

Related links & readings: 

Monodispersed Colloidal Spheres: Old Materials with New Applications

 

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