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Photochromism Memories and Switches
Chemical Reviews Special Thematic Issue Vol. 100, N°5, 2000
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This issue Edited by Masahiro Irie from the Department of
Chemistry and Biochemistry at Kyushu University, Fukuoka, Japan
Covers the latest progress and achievements in non
biological new and traditional organic photochromic molecules (with an exception of
bacteriorhodopsin) and their applications to optical switches and memories. Topics
includes photo optical switching devices made by Organic-Inorganic materials, optical
neural networks using photochromic memory media, photochromic mechanisms, non linear
optical properties of photochromic molecules and more...
For a complete file of contents and ordering information
visit the Web site of Chemical Reviews
New Nanocomposites : Putting organic function
"inside" the channel walls of periodic mesoporous silica
Tewodros Asefa, Chiaki Yoshina-Ishii, Mark J. MacLachlan, Geoffrey A. Ozin
Journal of Materials Chemistry, vol. 10, N° 8, 2000, 1751 |
The authors review an emerging materials chemistry field which allows using a "bottom
up" approach to functionalize and tailor at the molecular level Inorganic-Organic
interfaces. This new class of mesoporous Inorganic-Organic hybrids is formed by
condensation polymerization of (RO)3 - X - Si(OR)3 precursors
in presence of a liquid crystalline template. The resulting material is a monodisperse
hexagonally ordered channels with tunable size from 2 to 100 nm. By this way an
in situ
incorporation of the organic group X is formed which bridge bond the walls of the periodic
structure.
Direct incorporation of organic groups X such as methylene, ethane, ethylene,
benzene, thiophene, acetylene, ferrocene has been already demonstrated and there is no
reasons why other chemical groups with specific functions cannot be covalently integrated
into these structures.
This open the window for high functionalized materials. The X
groups which can be considered as spacers between the wall structure, could be selected to
either soften or harden the structure.
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Full color emission from II-VI Semiconductor Quantum
Dot-Polymer composites.
J. Lee, V. C. Sundar, J. R. Heine, M. G.
Bawendi, K. F. Jensen
Adv. Mater. 2000, 12, No. 15, 1102-1105
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Generally, Quantum dots suffer stability which most of the
time is re mediated by using a in situ caping process or by using a post synthetic grafting
technique. Even so the incorporation of such QD into a solid matrix is not straightforward.
The authors of this paper present a chemical route to produce stable QD polymer composites
with Photoluminescent quantum yields approaching the one found in dilute hexane solution of
the same QD. The composites are fabricated by chemical stabilization of synthesized II-VI
semiconductors QD ( (CdSe)ZnS and (CdS)ZnS) into polylauryl methacrylate matrice in
presence of tri-n-octylphosphine.
PL yield between 22 to 40 % was measured in respect to the QD size. Under a UV excitation
(which
can be provided by a commercial GaN Led) nearly pure colors in the visible range from 450
to 650 nm have been demonstrated.
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Photonic Crystals
By Greg Parker and Martin Charlton
Physics World, August 2000, 29-34
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Photonic crystal structures have a bright future. They have
all the ingredients to be in future telecommunications and information processing systems
what was the
semiconductors in the revolution of the electronic industry. This is an excellent
introduction to this exciting subject for all of us who do not necessarily want
to go in a depth analysis to understand how these device works.
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