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Prototype systems for rechargeable magnesium batteries
D. Aurbach, Z. Lu, A. Schechter, Y. Gofer, H. Gizbar, R. Turgeman, Y. Cohen, M. Moshkovich
& E. Levi Department of Chemistry, Bar-Ilan University, Israel
Nature, Vol 407, 2000, 724
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Did the Mg based batteries will replace in the near future the old lead-acid and
nickel-cadmium systems ? Development of Mg based batteries has been hindered by the
chemical activity of Mg itself and the difficulty of intercalating this element to the
cathode material host. Scientist at Bar-Ilan University in Israel have recently
developed a rechargeable Mg battery and show promise for applications by overcoming the
initial difficulties; The system comprise electrolyte solution based on Mg
organohaloaluminate salts, and MgxMo3S4 cathodes, into which Mg ions can be intercalated
reversibly, and with relatively fast kinetics. The authors concludes that with good
engineering it will be possible to obtain large, rechargeable Mg based batteries with
practical energy density considerably larger than 60 W h kg-1.
More about that story at Nature ScienceUpdate
brief news by David Adam
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Effect of additives on the structure of SiO2 sol-gel
spray coatings
C. Löser and C; Rüssel, Otto-Schott-Institut für Glaschemie,
Friedrich-Schiller-Universität, Jena (Germany)
Glastech. Ber. Sci.
Technol. 73, N° 9, 2000, 270
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Although spin and dip techniques are the most intensively investigated and used in a
commercial base for the manufacturing of sol-gel coatings , Spray deposition remains
a wide spread coating techniques which offer a large variety of technical potential.
Unfortunately spray technique has been little investigated for sol-gel coating and
little is know on how this technique could be used on making optical quality thin films. The
authors provides useful information on how to achieve this objective by using non volatile additives
to reduce the film roughness down to a few nm with excellent thickness uniformity across
the substrate.
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Optically Defined Multifunctional
Patterning of photosensitive thin film silica mesophases
D.A. Doshi, N.K. Huesing, M. Lu, H. Fan, Y. Lu, K. Simmons-Potter, B;G.
Potter Jr, A. J. Hurd, C.J. Brinker
Science vol 290,
2000, 107
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The ability to pattern porous thin films is
important for a number of applications, including sensor arrays, optics, and
microfluidic devices. The authors describe a photopatternig technique using
a photoacid generator compartimentalized within a silica-surfactant
mesophase which control local siloxane condensation. Selective etching of
unexposed regions is used to create gray scale pattering of refractive
index, pore size, surface area and wetting behaviour. An unprecedent pore
size control is achieved by this way down to 0.2 A°. Using this technique
one can imagine creating membranes separating Oxygen from Nitrogen.
More about that story : Ligth
used to control size nanopores , from Sandia National Laboratory News release
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