Sol-Gel
INM Information  
  Pilot Technology

 
Development of Large Area Electrochromic Sol-Gel Devices

Schematic layout of the electrochromic (EC) device

Institut für
Neue Materialien
gem. GmbH

Im Stadtwald, Geb.43
D-66123 Saarbrücken

http://www.inm-gmbh.de

Management
Tel.: ++49 681 9300-313
Fax: ++49 681 9300-223

Contact:
Dr. M. Mennig,
Physik und Chemie des Glases
Tel.: ++49 681 9300-394
Fax: ++49 681 9300-223


Objective
  • Development of large area electrochromic (EC) systems based on sol-gel techniques

Methods

  • Preparation of functional coating systems via sol-gel techniques: electrochromic layer: tungsten oxide; intercalation layer: cerium oxide-titanium dioxide; transparent electrolyte: inorganic-organic nanocomposite
  • Coating of transparent electrically conducting ITO-glasses (Indium-Tin-Oxide) or FTO-glasses (fluorine doped tin oxide, e.g. K-glass, TEC8) using dip-coating or spraying

Results

  • Cells in the format up to 50 x 80 cm2 can be routinely produced
  • Reversible variation in transmission from 70 % (550 nm, bleached state) down to
    21 -25 % (coloured state)

 


  • switching times t80 (t80: Time for 80 % of transmission change):
    60 s (colouration) and 30 s (bleaching) for EC-cells of 10 x 10 cm2;
    120 s (colouration), 70 s (bleaching) for EC-cells of 50 x 80 cm2

Applications

  • "Smart Windows"
  • Automotive glazing and sunroofs
  • Active and passive displays

Benefits

  • Energy saving for architectural and automotive glazing (air-conditioning costs in summer, heating costs in winter)
  • Privacy effects
  • Energy saving systems: only current flow during the switching period