Sol-Gel
INM Information
 
Laboratory Technology

 
Photochromic Coating Materials

Photochromic coatings on glass without and with UV-irradiation

Institut für
Neue Materialien
gem. GmbH

Im Stadtwald, Geb.43
D-66123 Saarbrücken
Germany

http://www.inm-gmbh.de

Management:
Tel.: ++49-681-9300-313
Fax: ++49-681-9300-223

Contact:
Dr. M. Mennig,
Physics and chemistry of glasses
Tel.: ++49-681-9300-394
Fax: ++49-681-9300-223


Objective
  • Development of photochromic coating materials based on organic photochromic dyes with response times of seconds, which can be applied on transparent substrates (glass, polymers) or on non transparent substrates (ceramics, polymers, paper) for the preparation of coatings with thickness of 5 - 50 m m

Method

  • Incorporation of spirooxazines, pyrans and fulgids into the matrix of an organic-inorganic composite, which is prepared by a specially developed sol-gel process

 


Results
  • Darkening from 90 % to 10 % transmission
  • By components of the matrix, the kinetic behaviour of the photochromic dye is adaptable to the different applications
  • Half life times for darkening and fading (t0,5) of 2 s - 10 min
  • Neutral tints (grey or brown) by mixing different photochromic dyes
  • High scratch resistance
  • High long term stability by special additives (decrease of the darkening DA0 to half of its initial value after 60 - 80 h of an accelerated suntest)