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Message Icon Topic: different phases of aluminium hydroxide(Topic Closed Topic Closed) Post Reply Post New Topic
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Joined: 10 March 2004
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bullet Topic: different phases of aluminium hydroxide
    Posted: 10 March 2004 at 4:02am

        I want to know the different phases that forms while heating the precursors for aluminium hydroxide. I am getting all the peaks of alpha-alumina at 1200 degree celsius. Pls give me the tranisition temperature also. My precursor has been prepared from aluminium nitrate and NH4OH.

 

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M.Prassas
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bullet Posted: 12 March 2004 at 7:40am

This is not a surprise. Above 1200°C most of aluminum hydroxides transforms to alpha-alumina which is the high temperature stable phase.
However below 1100°C a variety of phases occurs. The type and the structure of the phase appearing under heat treatment below 1100°C depends strongly on the initial aluminum hydroxide precursor.
There are 5 crystalline aluminum hydroxides (depending of the synthesis route):

  • Gibbsite
  • Bayerite
  • Nord-Strandite
  • Diaspore
  • Boehmite

With exception of Diaspore which by dehydroxylation leads directly to alpha-alumina (>800) all other hydroxides give you a number of crystalline phase in respect to the temperature

i.e
Gibbsite crystallize to Chi-alumina (300-600°C) then to kappa-alumina(750°C-950°C) and finally to alpha
For boehmite which is the most common phase by sol-gel you can have successively various crystalline forms from eta-alumina to gamma, delta, theta and finally alpha.

Hope this can help

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